publications / PATENTS / BOOK CHAPTERS
113. | "On the Mechanism of Acrylate and Propionate Silyl Esters Synthesis by Ruthenium-Catalyzed Coupling of CO2 with C2H4 in the Presence of Hydrosilanes: Combined Experimental and Computational Investigation”. Kunihiro, K.; Rajeshkumar, T.; Maron, L.; Heyte, S.; Paul, S.; Roisnel, T.; Carpentier, J.-F.; Kirillov, E. Mol. Cat. 2025, 570,114660. DOI link |
112. | “Hydrogenation of CO2 by a Tripodal Palladium Pincer Complex”. Biswas, N.; Lönnecke, P.; Kirillov, E.; Gelman, D. ACS Catal. 2024, 14,13163. DOI link |
111. | “Studies on the Coordination Patterns of Diamine-Bridged Tetraphenoxy Ligands with Group 3 and 4 Metals”. Chen, Y.; Qu, L.; Roisnel, T.; Cordier, M.; Yuan, D.; Yao, Y.; Kirillov, E. Inorg. Chem. 2024, 63, 12774. DOI link |
110. | “Dinuclear Group IV Metal Complexes based on a Bis(indenyl)-(E/Z)-Stilbene Platform: A Potential Prototype of “Photoswitchable” Catalysts for Olefin Polymerization”. Romero, N.; Chavagnan, T.; Roisnel, T.; Welle, A.; Kirillov, E.; Carpentier, J.-F. Dalton Trans. 2024, 53, 9452. DOI link |
109. | "Aluminum Complexes Supported by Ph2P-Functionalized Anilido-Pyridine Ligand Platform: Synthesis, Structure and Evaluation as Frustrated Lewis Pairs". Chandramohan, K. R. K.; Abdalghani, I.; Roisnel, T.; Kirillov, E. Eur. J. Inorg. Chem. 2024, 27, e202400089. DOI link |
108. | “A High-valent Ru-PCP Pincer Catalyst for Hydrosilylation Reactions”. Mujahed, S.; Gandolfo, D.; Vaccaro, L.; Kirillov, E.; Gelman, D. Mol. Cat. 2024, 553, 113586. DOI link |
107. | "Characterization of Modified Methylaluminoxane by Ion Mobility Spectrometry Mass Spectrometry and Ultra-High Resolution Fourier-Transform Ion Cyclotron Resonance Mass Spectrometry”. Naim, A.; Hubert-Roux, M.; Cirriez, V.; Welle, A.; Vantomme, A.; Kirillov, E.; Carpentier, J.-F.; Giusti, P.; Afonso, C. New J. Chem. 2023, 47, 21244. DOI link |
106. | “Hydrogenation of CO2 by a Bifunctional PC(sp3)P Iridium(III) Pincer Complex Equipped with Tertiary Amine as a Functional Group”. Gelman-Tropp, S.; Kirillov, E.; Hey-Hawkins, E.; Gelman, D. Chem. Eur. J. 2023, 29, e202301915. DOI link |
105. | “An Asymmetric Dinuclear Bis(ansa-Zirconocene) Complex: Synthesis and Performance in Olefin (co-)Polymerization”. Jende, L. N.; Roisnel, T.; Cirriez, V.; Welle, A.; Kirillov, E.; Carpentier, J. F. Catalysts 2023, 13, 1108. DOI link |
104. | “C1-Symmetric {Cyclopentadienyl/Indenyl}-Metallocene Catalysts: Synthesis, Structure, Isospecific Polymerization of Propylene and Stereocontrol Mechanism”. Theodosopoulou, D.; Alonso De La Pena, M.; Derhamine, S. A.; Douair, I.; Roisnel, T.; Cordier, M.; Piola, L.; Fernandez, A.; Welle, A.; Maron, L.; Carpentier, J.-F.; Kirillov, E. Dalton Trans. 2023, 52, 8620-8630. DOI link |
103. | “A High-valent Ru-PCP Pincer Catalyst for the Hydrogenation of Organic Carbonates”. Mujahed, S.; Richter, M. S.; Kirillov, E.; Hey-Hawkins, E.; Gelman, D. Isr. J. Chem. 2023, 63, e202300037. DOI link |
102. | “Comonomer-Controlled Synthesis of Long-Chain Branched (LCB)-Polyethylene.” Santoro, O.; Piola, L.; Mc Cabe, K.; Lhost, O.; Den Dauw, K.; Fernandez, A.; Welle, A.; Maron, L.; Carpentier, J.-F.; Kirillov, E. Eur. Pol. J. 2022, 173, 111257. DOI link |
101. | “Meso - and Rac-[bis(3-phenyl-6-tert-butylinden-1-yl)dimethylsilyl]zirconium Dichloride: Precatalysts for the Production of Differentiated Polyethylene Products with Enhanced Properties.” |
100. | “Group 12 and 13 Metal-Alkenyl Promoted Generation of Long-Chain Branching in Metallocene-Based Polyethylene.” Santoro, O.; Piola, L.; Mc Cabe, K.; Lhost, O.; Den Dauw, K.; Fernandez, A.; Welle, A.; Maron, L.; Carpentier, J.-F.; Kirillov, E. Eur. Pol. J. 2022, 173, 111257. DOI link |
99. | “Upgrading Toughness and Glass Transition Temperature of Polydicyclopentadiene Upon Addition of Styrene-Ethylene-Butylene-Styrene Thermoplastic Elastomer.” Beuguel, Q.; Kirillov, E.; Carpentier, J.-F.; Guillaume, S. M. ACS Appl. Polym. Mater. 2022, 4, 2251-2255. DOI link |
98. | “Propylene Polymerization and Deactivation Processes with Isoselective {Cp/Flu} Zirconocene Catalysts”. Desert, X.; Roisnel, T.; Dorcet, V.; Den Dauw, K.; Vantomme, A.; Welle, A.; Carpentier, J.-F.; Kirillov, E. Catalysts 2021, 11, 959-978. DOI link |
97. | “Al-Alkenyl-Induced Formation of Long-Chain Branched Polyethylene via Coordinative Tandem Insertion and Chain-Transfer Polymerization Using (nBuCp)2ZrCl2/MAO Systems: An Experimental and Theoretical Study”. Santoro, O.; Piola, L.; Mc Cabe, K.; Lhost, O.; Den Dauw, K.; Vantomme, A.; Welle, A.; Maron, L.; Carpentier, J.-F.; Kirillov, E. Eur. Pol. J. 2021, 154, 110567. DOI link |
96. | “Ruthenium-Catalyzed Coupling Reactions of CO2 with C2H4 and Hydrosilanes towards Silyl Esters”. Kunihiro,K.; Heyte, S.; Paul, S.; Roisnel, T.; Carpentier, J.-F.; Kirillov, E. Chem. Eur. J. 2021, 27, 3997-4003. DOI link |
95. | “{Cyclopentadienyl/Fluorenyl}-Group 4 ansa-metallocene Catalysts for Production of Tailor-made Polyolefins”. |
94. | “Rare-Earth Metal Complexes Supported by Polydentate Phenoxy-Type Ligand Platforms: C-H Activation Reactivity and CO2/Epoxide Copolymerization Catalysis”. |
93. |
“Long-Chain Branched Polyethylene via Coordinative Tandem Insertion and Chain-Transfer Polymerization Using rac-{EBTHI}ZrCl2/MAO/Al-alkenyl Combinations: An Experimental and Theoretical Study”. |
92. |
“Recent advances in applications of vinyl ether monomers for precise synthesis of custom-tailored polymers”. |
91. |
“Asymmetric Allylic Alkylation of β-Ketoesters via C–N Bond Cleavage of N-Allyl-N-methylaniline Derivatives Catalyzed by a Nickel–Diphosphine System”. |
90. |
“Reduction of CO2 by Hydrosilanes in the Presence of Formamidinates of Groups 13 and 12 Elements”. |
89. |
“Paraffin-Inert Atmospheric Solid Analysis probe (piASAP): A Fast and Easy Approach to Characterize Extremely Air-Sensitive Organometallic Complexes by Mass Spectrometry.” |
88. |
“Zirconocene-Catalyzed Polymerization of α-Olefins: When Intrinsic Higher Activity is Flawed by Rapid Deactivation”. |
87. |
“Quantification of Active Sites in Single-Site Group 4 Metal Olefin Polymerization Catalysis”. |
86. |
“Synthesis, APPI Mass-Spectrometric Characterization, and Polymerization Studies of Group 4 Dinuclear Bis(ansa-metallocene) Complexes”. |
85. |
“Trinuclear Tris(ansa-metallocene) complexes of Zirconium and Hafnium for Olefin Polymerization”. |
84. |
“A Theoretical Outlook on the Stereoselectivity Origins of Isoselective Zirconocene Propylene Polymerization Catalysts”. |
83. |
“Stereoselective Copolymerization of Styrene with Terpenes Catalyzed by an Ansa-Lanthanidocene Catalyst: Access to New Syndiotactic Polystyrene-Based Materials”. |
82. |
“Synthesis and Structural Characterization of Zirconium Complexes Supported by Tridentate Pyrrolide-Imino Ligands with Pendant N-, O- and S-donor Groups and Their Application in Ethylene Polymerization”. |
81. |
“Experimental and Computational Investigations on Highly Syndioselective Styrene-Ethylene Copolymerization Catalyzed by Allyl ansa-Lanthanidocenes”. |
80. |
“Substitution Effects in Highly Syndioselective Styrene Polymerization Catalysts Based on Single-Component Allyl ansa-Lanthanidocenes: An Experimental and Theoretical Study”. |
79. |
“Engineering of Syndiotactic and Isotactic-Polystyrene Based Copolymers via Stereoselective Catalytic Polymerization”. |
78. |
“Conformationally Dynamic Titanium and Zirconium Cationic Complexes of Bis(naphthoxy)pyridine ligands: Structure, “Oscillation” and Olefin Polymerization Catalysis”. |
77. |
“Polymerization of Sterically Hindered Alpha-Olefins with Single-Site Group 4 Metal Catalyst Precursors”. |
76. |
“Scandium and Yttrium Complexes of an Hybrid Phenoxy-Amidopyridinate Ligand. Use in ROP of Racemic Lactide”. |
75. |
“Synthesis and Structure of First Discrete Dinuclear Cationic Aluminum Complexes”. |
74. |
“Yb(II) Triple-Decker Complex with the μ-Bridging Naphthalene Dianion [CpBn5Yb(DME)]2(μ-η4:η4-C10H8). Oxidative Substitution of [C10H8]2– by 1,4-Diphenylbuta-1,3-diene and P4 and Protonolysis of the Yb–C10H8 Bond by PhPH2”. |
73. |
“Tandem C(sp2)–OMe Activation / C(sp2)–C(sp2) Coupling in Early Transition Metal Complexes: Aromatic C−O Activation beyond Late Transition Metals”. |
72. |
"Highly Stereocontrolled Ring-Opening Polymerization of racemic-Alkyl beta-Malolactonates Mediated by Yttrium [Amino-alkoxy-bis(phenolate)] Complexes". |
71. |
“Discrete Ionic Complexes of Highly Isoselective Zirconocenes. Solution Dynamics, Trimethylaluminum Adducts, and Implications in Propylene Polymerization”. |
70. |
“Ni(II) complexes bearing pyrrolide-imine ligands with pendant N-, O- and S-donor groups: synthesis, structural characterization and use in ethylene oligomerization”. |
69. |
“Carboxylic acid derivatives via catalytic carboxylation of unsaturated hydrocarbons: whether the nature of a reductant may determine the mechanism of CO2 incorporation?” |
68. |
“Ethylene oligomerization promoted by chromium complexes bearing pyrrolide–imine–amine/ether tridentate ligands”. |
67. |
”Heterobi- and -trimetallic Ion Pairs of Zirconocene-Based Isoselective Olefin Polymerization Catalysts with AlMe3”. |
66. |
”Beyond Stereoselectivity, Switchable Catalysis: Some of the Last Frontier Challenges in Ring-Opening Polymerization of Cyclic Esters”. |
65. |
”Syndioselective ring-opening polymerization and copolymerization of trans-1,4-cyclohexadiene carbonate mediated by achiral metal- and organo-catalysts”. |
64. |
”Are Solvent and Dispersion Effects Crucial in Olefin Polymerization DFT Calculations? Some Insights from Propylene Coordination and Insertion Reactions with Group 3 and 4 Metallocenes”. |
63. |
“Zinc, aluminum and group 3 metal complexes of sterically demanding naphthoxy-pyridine ligands: Synthesis, structure, and use in ROP of racemic lactide and β-butyrolactone”. |
62. |
“iPP-sPP Stereoblocks or Blends? Studies on the Synthesis of Isotactic-Syndiotactic Polypropylene Using Single C1- Symmetric {Ph2C-(Flu)(3-Me3Si-Cp)}ZrR2 Metallocene Precatalysts”. |
61. |
“Zirconocene-catalyzed stereoselective cyclocopolymerization of 2-methyl-1,5-hexadiene with propylene”. |
60. |
“Scandium versus yttrium{amino-alkoxy-bis(phenolate)} complexes for the stereoselective ring-opening polymerization of racemic lactide and β-butyrolactone”. |
59. |
"Enantiopure Isotactic PCHC synthesized by Ring-Opening Polymerization of Cyclohexene Carbonate". |
58. |
“Neutral and Cationic Alkyl and Amido Group 3 Metal Complexes of Amidine-Amidopyridinate Ligands: Synthesis, Structure and Polymerization Catalytic Activity”. |
57. |
“Discrete O-Lactate and β-Alkoxybutyrate Aluminum Pyridine–Bis(naphtholate) Complexes: Models for Mechanistic Investigations in the Ring-Opening Polymerization of Lactides and β-Lactones”. |
56. |
“Yttrium- and Aluminum-Bis(phenolate)pyridine Complexes: Catalysts and Model Compounds of the Intermediates for the Stereoselective Ring-Opening Polymerization of racemic Lactide and -Butyrolactone”. |
55. |
“Dinuclear vs. Mononuclear Complexes: Accelerated, Metal-dependent Ring-Opening Polymerization of Lactide”. |
54. |
“{Phenoxy-Imine}-Aluminum versus Indium Complexes for the immortalROP of Lactide. Different Stereocontrol, Different Mechanisms”. |
53. |
“Gallium and Indium Complexes for Ring-Opening Polymerization of Cyclic Ethers, Esters and Carbonates”. |
52. |
“Alkyl Yttrium Complexes of Amidine-amidopyridinate Ligands. Intramolecular C(sp3)-H Activation and Reactivity Studies”. |
51. |
“Old and New C1-Symmetric Group 4 Metallocenes {(R1R2C)-(R2’R3’R6’R7’-Flu)(3-R3-5-R4-C5H2)}ZrCl2: From Highly Isotactic Polypropylenes to Vinyl End-Capped Isotactic-Enriched Oligomers”. |
50. |
“Meerwein–Ponndorf–Verley-Type Reduction Processes in Aluminum and Indium Isopropoxide Complexes of Imino-Phenolate Ligands”. |
49. |
“Synthesis and Structural Diversity of Group 4 Metal Complexes with Multidentate Tethered Phenoxy-Amidine and Phenoxy-Amidinate Ligands”. |
48. |
"Cyclodextrin-Centered Polyesters: Controlled Ring-Opening Polymerization of Cyclic Esters from β-Cyclodextrin-Diol". |
47. |
"Indium Complexes of Fluorinated Dialkoxy-Diimino Salen-like Ligands for Ring-Opening Polymerization of racemic Lactide: How does Indium Compare to Aluminum?" |
46. |
“Lanthanide borohydrides supported by an ansa-bis(amidinate) ligand with a rigid naphthalene linker: Synthesis, structure and catalytic activity in ring-opening polymerization of lactide”. |
45. |
"Rare Earth Complexes with Multidentate Tethered Phenoxy-Amidinate Ligands: Synthesis, Structure and Activity in Ring-Opening Polymerization of Lactide". |
44. |
“Chiral-at-ansa-Bridged Group 4 Metallocene Complexes {(R1R2C)-(3,6-tBu2Flu)(3-R3-5-Me-C5H2)}MCl2: Synthesis, Structure, Stereochemistry, and Use in Highly Isoselective Propylene Polymerization”. |
43. |
“Exploring Electronic versus Steric Effects in Stereoselective Ring-Opening Polymerization of Lactide and b-Butyrolactone with Amino-Alkoxy-Bis(phenolate) Yttrium Complexes”. |
42. |
“New C1-Symmetric Ph2C-bridged multisubstituted ansa-zirconocenes for highly isospecific propylene polymerization: synthetic approach via activated fulvenes”. |
41. |
“A DFT investigation of the tacticity control during styrene polymerization catalyzed by single-component allyl ansa-lanthanidocenes {(C5H4-CMe2(9-C13H8)}Ln(C3H5)”. |
40. |
“Discrete allyl complexes of group 3 metals and lanthanides”. |
39. |
“Group 3 metal complexes supported by tridentate pyridine- and thiophene-linked bis(naphtholate) ligands: synthesis, structure, and use in stereoselective ring-opening polymerization of racemic lactide and beta-butyrolactone”. |
38. |
“Group 4 post-metallocene complexes incorporating tridentate silyl-substituted bis(naphthoxy)pyridine and bis(naphthoxy)thiophene ligands: probing systems for ”oscillating” olefin polymerization catalysis”. |
37. |
"Chromium(III) complexes of sterically crowded bidentante {ONR} and tgridentate {ONNR} naphthoxy-imine ligands: syntheses, structures and use in ethylene oligomerization”. |
36. |
“On the initiation mechanism of syndiospecific stryrene polymerization catalyzed by single-component ansa-lanthanidocenes”. |
35. |
“Group 4 Metal Complexes of Fluorous (Di)Alkoxide-(Di)Imino Ligands: Synthesis, Structure, Olefin Polymerization Catalysis, and Decomposition Pathways”. |
34. |
“Group 3 metal complexes of salen-like fluorous dialkoxy-diimino ligands: synthesis, structure and application in ring-opening polymerization of rac-lactide and rac-b-butyrolactone". |
33. |
“Aluminum complexes of fluorinated dialkoxy-diimino salen-like ligands: syntheses, structures and use in ring-opening polymerization of cyclic esters”. |
32. |
“Stereocontrolled styrene-isoprene copolymerization and styrene-ethylene-isoprene terpolymerization with a single-component allyl ansa-Neodymocene Catalyst”. |
31. |
“Modified Syndiotactic Polystyrenes from Single-Site Rare-Earth Catalysts”. |
30. |
“Synthesis, structures, dynamics and ethylene polymerization activity of nickel complexes containing an ortho-methoxy-aryl diphosphine ligand”. |
29. |
“Haptotropic rearrangements in sandwich (fluorenyl)(cyclopentadienyl) iron and ruthenium complexes”. |
28. |
“Group 3 and 4 single-site catalysts for stereospecific polymerization of styrene”. |
27. |
“Convenient synthesis of mono- and di-β-hydroxy-β-bis(trifluoromethyl)-(di)imines from β-hydroxy-β-bis(trifluoromethyl)-ketones and (di)amines”. |
26. |
“Highly isospecific styrene polymerization catalyzed by single-component bridged bis(indenyl) allyl group 3 complexes”. |
25. |
“Binary ansa-lanthanidocenes/dialkylmagnesium systems versus single-component catalyst: controlled synthesis of end-capped syndiotactic oligostyrenes”. |
24. |
“Allyl ansa-lanthanidocenes: single-component, single-site catalysts for controlled syndiospecific styrene and styrene-ethylene (co)polymerization”. |
23. |
“Chiral fluorous dialkoxy-diamino zirconium complexes: synthesis and use in stereospecific polymerization of 1-hexene”. |
22. |
“Syndiotactic-enriched propylene-styrene copolymers using fluorenyl-based half-titanocene catalysts”. |
21. |
“Ansa-metallocene and half-sandwich somplexes of group 3 metals and lanthanides incorporating fluorenyl-based ligands: from synthesis to catalytic applications”. |
20. |
“Groups 2 and 3 metal complexes incorporating fluorenyl ligands”. |
19. |
“Highly syndiospecific polymerization of styrene catalyzed by allyl lanthanide complexes”. |
18. |
“Synthesis, structure and polymerization activity of neutral halide, alkyl and hydrido yttrium complexes of isopropylidene-bridged cyclopentadienyl-fluorenyl ligands”. |
17. |
“[η5:η1-(3,6-tBu2Flu)SiMe2NtBu]Y(η1-NC5H6)(py)2: a 1,4-hydride addition product to pyridine that brings evidence for the first group 3 metal fluorenyl-hydrido complex”. |
16. |
“[(Cp-CMe2-Flu)2Ln]–[Li(ether)n]+ (Ln = Y, La): complexes with unusual coordination modes of the fluorenyl ligand and the first examples of lis(ansa)lanthanidocenes”. |
15. |
“Group 3 metal "constrained geometry" complexes of the fluorenyl-based ligands [(3,6-tBu2Flu)SiR2NtBu]: synthesis, structural characterization and polymerization activity”. |
14. |
“A new half-sandwich Yb(II) complex with the tridentate cyclopentadienyl ligand [C5H4CH2CH(O)CH2OBu]2-: synthesis, self-assembly of a tetranuclear cuban-like framework {[(η5-C5H4)CH2CH(η1-O)CH2O-nBu)]Yb}4 and oxidative alkylation by Me2Hg to the Yb(III) derivative [(η5-C5H4)CH2CH(η1-O)CH2O-nBu]YbMe(thf)”. |
13. |
“Half-sandwich complexes of lanthanides with tridentate ligands [RCH2CH(O)CH2OBu]2- (R = C5H4, 1-C9H6): synthesis, structures, and properties. The crystal structure of the complex {[(η5-C5H4)CH2CH(η2:η1-O)CH2OBu]LaN(SiMe3)2}2”. |
12. |
“Catalytic activity of some organolanthanoid derivatives in the styrene and propene polymerization”. |
11. |
“Fluorenyl and ansa-dimethylsilyl-bis(fluorenyl) derivatives of divalent ytterbium and samarium - synthesis and structure of the first mixed – ligand LnII classic sandwich complex (C13H9)(C5Me5)Yb(DME)”. |
10. |
“(C9H7)YbI(DME)2, the first indenyl half-sandwich complex of divalent ytterbium”. |
9. |
“Interaction of the naphthalene ytterbium complex C10H8Yb(THF)2 with cyclopentadienyl-substituted alkohols and amines – a convenient synthetic route to half-sandwich complexes of divalent ytterbium”. |
8. |
“Molecular hydrides of samarium and europium LnH2(THF)2 (Ln = Sm, Eu): synthesis and properties”. |
7. |
“Investigation of reactions of some halides, cyclopentadienyl-dichlorides and biscyclopentadienylchlorides of lanthanides with radical-anion adducts of trans-stilbene and alkaline metals [PhCHCHPh]-.M+ (M = Li, Na)”. |
6. |
“Attempted synthesis of divalent neodymium derivatives. crystal structure of the Nd(III) complex [{NdCl2(2,4,6-tBu3C6H2O)(μ-Cl)(THF)}Li(THF)2]2”. |
5. |
“Divalent compounds of thulium, neodymium, and dysprosium”. |
4. |
“A new bifunctional ligand: C5Me4HSiMe2OSiMe2O2-. Synthesis, properties and crystal structure of the first Yb(II) half-sandwich complex with a heterobidentate cyclopentadienyl ligand, [{(η5-C5Me4)SiMe2OSiMe2(η1-O)}Yb(thf)]2”. |
3. |
“Synthesis, properties and crystal structure of complex Cp2Yb(DAD)”. |
2. |
“Synthesis, properties and reactivity of stilbene ytterbium complex (PhCHCHPh)Yb(THF)3. Crystal structure of (2,4,6-But3C6H2O)2Yb(THF)3“. |
1. |
“Oxidation of magnesium in the presence of coordinating solvents“. |
PATENTS
28. | “Dual Catalyst Compositions and Polymerization Process”. Giffin, K.; Carpentier, J.-F.; Kirillov, E.; Welle, A.; Cirriez, V. (Univ Rennes 1, CNRS and TotalEnergies OneTech Belgium); WO2023099528 A1 (2023-06-08). Espacenet |
27. | “Dual Catalyst Compositions”. Giffin, K.; Carpentier, J.-F.; Kirillov, E.; Welle, A.; Cirriez, V. (Univ Rennes 1, CNRS and TotalEnergies OneTech Belgium); WO2023099525 A2 (2023-06-08). Espacenet |
26. | “New Metallocene Catalyst and Use Thereof”. Coustham, T.; Carpentier, J.-F.; Kirillov, E.; Theodosopoulou, D.; Welle, A.; Piola, L. (Univ Rennes 1, CNRS and Total Research Technology Feluy); WO2022248517 A1 (2022-12-01). Espacenet |
25. | “Process for preparing ethylene polymers having long chain branches in the presence of catalyst system comprising bridged metallocene and alkenyl-aluminum”. Welle, A.; Carpentier, J.-F. ; Kirillov, E.; Piola, L.; Santoro, O. (Univ Rennes 1, CNRS and Total Research Technology Feluy); WO2022029213 A1 (2022-02-10). |
24. | “Propylene polymers having long chain branches, preparation process and catalyst system”. Welle, A.; Carpentier, J.-F. ; Kirillov, E.; Piola, L.; Santoro, O. (Univ Rennes 1, CNRS and Total Research Technology Feluy); WO2022029212 A1 (2022-02-10). |
23. | “New compounds suitable as catalysts for polymerization reactions”. Welle, A.; Vantomme, A.; Carpentier, J.-F.; Nuria, R.; Kirillov, E. (Univ Rennes 1 and Total Petrochemicals); WO2019048561 A1 (2019-03-14). |
22. | “Process for preparing polyethylene using bis(metallocene) compound catalysts”. Welle, A.; Vantomme, A.; Carpentier, J.-F.; Schnee, G.; Miserque, O.; Kirillov, E. (Univ Rennes 1 and Total Petrochemicals); WO2018046567 A1 (2018-03-15). |
21. | “Process for preparing polyethylene using bis(metallocene) compound catalysts”. Welle, A.; Vantomme, A.; Carpentier, J.-F.; Schnee, G.; Miserque, O.; Kirillov, E. (Univ Rennes 1 and Total Petrochemicals); WO2018046566 A1 (2018-03-15). |
20. | “Process for preparing polypropylene using bis(metallocene) catalysts”. Welle, A.; Vantomme, A.; Carpentier, J.-F.; Schnee, G.; Miserque, O.; Kirillov, E. (Univ Rennes 1 and Total Petrochemicals); WO2018046568 A1 (2018-03-15). |
19. | “Long-chain-branched polypropylene prepared with metallocene-based active catalyst systems”. Bader, M.; Carpentier, J.-F.; Kirillov, E.; Lhost, O.; Lamotte, C.; Den Dauw, K. (Univ Rennes 1 and Total Petrochemicals); WO2015082709 A1 (2015-06-11). |
18. |
“Polypropylene having improved elongational properties”. Bader, M.; Carpentier, J.-F.; Kirillov, E.; Lhost, O.; Ribour, D. (Univ Rennes 1 and Total Petrochemicals); WO2013060810 A1 (2013-05-02). |
17. |
“Fluorinated alkoxy-imino catalyst components”. Carpentier, J.-F.; Kirillov, E.; Thomas, C.T.; Razavi, A.; Marquet, N. (Univ Rennes 1 and Total Petrochemicals); US8026192 B2 (2011-09-27). |
16. |
“Preparation of mono-aryl-substituted methylene-bridged substituted cyclopentadienyl-fluorenyl ligands and zirconium complexes derived thereof”. Carpentier, J.-F.; Kirillov, E.; Marquet, N.; Razavi, A. (Univ Rennes 1 and Total Petrochemicals); EP2204375 A1 (2010-07-07). |
15. |
“Preparation of Long-Chain Branched Isotactic Polypropylene”. Carpentier, J.-F.; Kirillov, E.; Marquet, N.; Razavi, A. (Univ Rennes 1 and Total Petrochemicals); EP2196481 A1 (2010-06-16); WO2010066906 A2 (2010-06-17); US20110306739 A1 (2011-12-15). |
14. |
“Sterically encumbered bidentate and tridentate naphthoxy-imine metallic complexes“. Carpentier, J.-F.; Kirillov, E.; Razavi, A. (Univ Rennes 1 and Total Petrochemicals); EP2113507 A1 (2009-11-04); WO2009133026 A1 (2009-11-05); US8492493 B2 (2013-07-23). |
13. |
“Post-Metallocene complexes based on bis(naphthoxy)pyridine and bis(naphthoxy)thiophene ligands for the polymerisation of ethylene and alpha-olefins”. Carpentier, J.-F.; Kirillov, E.; Razavi, A. (Univ Rennes 1 and Total Petrochemicals); EP2093229 A1 (2009-08-26); WO2009106458 A1 (2009-09-03); US8519070 B2 (2013-08-27). |
12. |
“Group 3 post-metallocene complexes based on bis(naphthoxy)pyridine and bis(naphthoxy)thiophene ligands for the ring-opening polymerisation of polar cyclic monomers“. Carpentier, J.-F.; Kirillov, E.; Razavi, A. (Univ Rennes 1 and Total Petrochemicals); EP2093242 A1 (2009-08-26); WO2009106459 A1 (2009-09-03); US8436133 B2 (2013-05-07). |
11. |
“Isospecific styrene polymerization using ansa-bis(indenyl) allyl lanthanide complex”. Rodrigues, A.-S.; Carpentier, J.-F.; Razavi, A.; Kirillov, E. (Univ Rennes 1 and Total Petrochemicals); EP1985619 A1 (2008-10-29). |
10. |
“Preparation of diphenyl-bridged substituted cyclopentadienyl-fluorenyl ligands for polymerization catalysts”. Razavi, A.; Kirillov, E.; Carpentier, J.-F.; (Univ Rennes 1 and Total Petrochemicals); EP1903061 A1 (2008-03-26). |
9. |
“Fluorinated alkoxy-imino olefin polymerization catalyst components“. Carpentier, J.-F.; Kirillov, E.; Thomas, C.T.; Razavi, A. (Univ Rennes 1 and Total Petrochemicals); WO2008031894 A1 (2008-03-20). |
8. |
“Fluorinated dialkoxy-diimino olefin polymerization catalyst components“. Carpentier, J.-F.; Kirillov, E.; Thomas, C.T.; Razavi, A. (Univ Rennes 1 and Total Petrochemicals). WO2008031890 A1 (2008-03-20). |
7. |
“Neutral ansa-bis(indenyl) allyl lanthanide complexes for stereospecific polymerization of styrene”. Carpentier, J.-F.; Kirillov, E.; Rodrigues, A.-S.; Razavi, A. (Univ Rennes 1 and Total Petrochemicals); EP1818337 A1 (2007-08-15). |
6. |
“Preparation of styrene-isoprene and of styrene-isoprene-ethylene copolymers”. Carpentier, J.-F.; Kirillov, E.; Razavi, A. (Univ Rennes 1 and Atofina); EP1777240 A1 (2007-04-25). |
5. |
“Carbon bridged cyclopentadienyl-fluorenyl ligands”. Kirillov, E.; Gladysz, J. A.; Razavi, A. (Friedrich-Alexander Universität Erlangen-Nürnberg and Atofina); WO2006134098 A1 (2006-12-21). |
4. |
”Preparation of styrene homopolymers and styrene-ethylene copolymers using lanthanide metallocene catalyst”. Carpentier, J.-F.; Kirillov, E.; Razavi, A. (Univ Rennes 1 et Atofina); EP1582536 A1 (2005-10-05). |
3. |
“Catalytic components with constrained geometry comprising a fluorenyl ligand and based on Group IIIB metals”. Carpentier, J.-F.; Kirillov, E.; Razavi, A. (Univ Rennes 1 and Atofina); FR2852015 A1 (2004-09-10); US Pat. US 7,241,849 B2 (06/01/2006). |
2. |
“Metallocenes bridged with Group III elements and based on cyclopentadienyl-fluorenyl ligands”. Carpentier, J.-F.; Kirillov, E.; Razavi, A. (Univ Rennes 1 and Atofina); FR2850386 A1 (2004-07-30); US Pat. US 7,309,748 B2 (16/11/2006). |
1. |
“Metallocenes bridged with Group III elements and based on cyclopentadienyl-fluorenyl ligands”. Carpentier, J.-F.; Kirillov, E.; Razavi, A. (Univ Rennes 1 and Atofina); FR2849654 A1 (2004-07-09). |
BOOK CHAPTERS
1. |
Stereoselective Polymerization (chapter 3.21; pp 931-971) J.-F. Carpentier and E. Kirillov, in Science of Synthesis, Stereoselective Synthesis (3 vol), Vol. 2010/9, Ed.: J. G. de Vries, P. A. Evans, G. A. Molander; Houben-Weyl E21, Thieme, June 2011, ISBN (Americas): 9783131541314; ISBN (EUR, Asia, Africa, AUS): 9783131541314. |
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2. |
Metal Phenolates as Polymerization Catalysts J.-F. Carpentier, E. Kirillov, Y. Sarazin, in PATAI’S Chemistry of Functional Groups, Online 2009–2012 John Wiley & Sons, Ltd. (Ed. Zabicky, J.). From Chemistry of Metal Phenolates (2014), 2, 839-911. |
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3. |
Metallocene Catalysts for Stereospecific Olefin Polymerization E. Kirillov, in Encyclopedia of Polymers, Polymeric Materials, and Polymer Technology, Taylor & Francis Group (CRC Press - Routledge) (Ed. M. K. Mishra). In press. |
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