Evgueni Kirillov: Publications

publications / PATENTS / BOOK CHAPTERS


106.	Hydrogenation of CO2 by a Bifunctional PC(sp3)P Iridium(III) Pincer Complex Equipped with Tertiary Amine as a Functional Group”. Gelman-Tropp, S.; Kirillov, E.; Hey-Hawkins, E.; Gelman, D. Chem. Eur. J. 2023, accepted.
105.	“An Asymmetric Dinuclear Bis(ansa-Zirconocene) Complex: Synthesis and Performance in Olefin (co-)Polymerization”. Jende, L. N.; Roisnel, T.; Cirriez, V.; Welle, A.; Kirillov, E.; Carpentier, J. F. Catalysts 2023, 13, 1108. DOI link
104.	“C1-Symmetric {Cyclopentadienyl/Indenyl}-Metallocene Catalysts: Synthesis, Structure, Isospecific Polymerization of Propylene and Stereocontrol Mechanism”. Theodosopoulou, D.; Alonso De La Pena, M.; Derhamine, S. A.; Douair, I.; Roisnel, T.; Cordier, M.; Piola, L.; Fernandez, A.; Welle, A.; Maron, L.; Carpentier, J.-F.; Kirillov, E. Dalton Trans. 2023, 52, 8620-8630. DOI link
103.	“A High-valent Ru-PCP Pincer Catalyst for the Hydrogenation of Organic Carbonates”. Mujahed, S.; Richter, M. S.; Kirillov, E.; Hey-Hawkins, E.; Gelman, D. Isr. J. Chem. 2023, 63, e202300037. DOI link
102.	“Comonomer-Controlled Synthesis of Long-Chain Branched (LCB)-Polyethylene.” Santoro, O.; Piola, L.; Mc Cabe, K.; Lhost, O.; Den Dauw, K.; Fernandez, A.; Welle, A.; Maron, L.; Carpentier, J.-F.; Kirillov, E. Eur. Pol. J. 2022, 173, 111257. DOI link
101.	“Meso - and Rac-[bis(3-phenyl-6-tert-butylinden-1-yl)dimethylsilyl]zirconium Dichloride: Precatalysts for the Production of Differentiated Polyethylene Products with Enhanced Properties.” Giffin, K. Cirriez, V.; Santoro, O.; Welle, A.; Kirillov, E.; Carpentier, J.-F. Special Issue "Polyolefins: The Ever-Thriving Thermoplastics", Polymers 2022, 14, 2217. DOI link
100.	“Group 12 and 13 Metal-Alkenyl Promoted Generation of Long-Chain Branching in Metallocene-Based Polyethylene.” Santoro, O.; Piola, L.; Mc Cabe, K.; Lhost, O.; Den Dauw, K.; Fernandez, A.; Welle, A.; Maron, L.; Carpentier, J.-F.; Kirillov, E. Eur. Pol. J. 2022, 173, 111257. DOI link
99.	“Upgrading Toughness and Glass Transition Temperature of Polydicyclopentadiene Upon Addition of Styrene-Ethylene-Butylene-Styrene Thermoplastic Elastomer.” Beuguel, Q.; Kirillov, E.; Carpentier, J.-F.; Guillaume, S. M. ACS Appl. Polym. Mater. 2022, 4, 2251-2255. DOI link
98.	“Propylene Polymerization and Deactivation Processes with Isoselective {Cp/Flu} Zirconocene Catalysts”. Desert, X.; Roisnel, T.; Dorcet, V.; Den Dauw, K.; Vantomme, A.; Welle, A.; Carpentier, J.-F.; Kirillov, E. Catalysts 2021, 11, 959-978. DOI link
97.	“Al-Alkenyl-Induced Formation of Long-Chain Branched Polyethylene via Coordinative Tandem Insertion and Chain-Transfer Polymerization Using (nBuCp)2ZrCl2/MAO Systems: An Experimental and Theoretical Study”. Santoro, O.; Piola, L.; Mc Cabe, K.; Lhost, O.; Den Dauw, K.; Vantomme, A.; Welle, A.; Maron, L.; Carpentier, J.-F.; Kirillov, E. Eur. Pol. J. 2021, 154, 110567. DOI link
96.	“Ruthenium-Catalyzed Coupling Reactions of CO2 with C2H4 and Hydrosilanes towards Silyl Esters”. Kunihiro,K.; Heyte, S.; Paul, S.; Roisnel, T.; Carpentier, J.-F.; Kirillov, E. Chem. Eur. J. 2021, 27, 3997-4003. DOI link
95.	“{Cyclopentadienyl/Fluorenyl}-Group 4 ansa-metallocene Catalysts for Production of Tailor-made Polyolefins”. Kirillov, E.; Carpentier, J.-F. Chem. Rec. 2021, 21, 357-375. DOI link
94.	“Rare-Earth Metal Complexes Supported by Polydentate Phenoxy-Type Ligand Platforms: C-H Activation Reactivity and CO2/Epoxide Copolymerization Catalysis”. Qu, L.; Roisnel, T.; Cordier, M.; Yuan, D.; Yao,Y.; Zhao, B.;Kirillov, E. Inorg. Chem. 2020, 69, 16976-16987. DOI link
93.	“Long-Chain Branched Polyethylene via Coordinative Tandem Insertion and Chain-Transfer Polymerization Using rac-{EBTHI}ZrCl2/MAO/Al-alkenyl Combinations: An Experimental and Theoretical Study”. Santoro, O.; Piola, L.; Mc Cabe, K.; Lhost, L.; Den Dauw, K.; Vantomme, A.; Welle, A.; Maron, L.; Carpentier, J.-F.; Kirillov, E. Macromolecules 2020, 53, 8847-8857. DOI link
92.	“Recent advances in applications of vinyl ether monomers for precise synthesis of custom-tailored polymers”. Kirillov, E.; Rodygin, K. Ananikov, V. Eur. Pol. J. 2020, 136, 109872. DOI link
91.	“Asymmetric Allylic Alkylation of β-Ketoesters via C–N Bond Cleavage of N-Allyl-N-methylaniline Derivatives Catalyzed by a Nickel–Diphosphine System”. Nagae, H.; Xia, J.; Kirillov, E.; Higashida, K.; Shoji, K.; Boiteau, V.; Zhang, W. ; Carpentier, J.-F.; Mashima, K. ACS Catal. 2020, 10, 5828-5839. DOI link
90.	“Reduction of CO2 by Hydrosilanes in the Presence of Formamidinates of Groups 13 and 12 Elements”. Huang, W.; Roisnel, T. Dorcet, V.; Orione, C.; Kirillov, E. Organometallics 2020, 39, 698-710. DOI link
89.	“Paraffin-Inert Atmospheric Solid Analysis probe (piASAP): A Fast and Easy Approach to Characterize Extremely Air-Sensitive Organometallic Complexes by Mass Spectrometry.” Naim, A.; Farenc, M.; Hubert-Roux, M.; Chavagnan, T.; Cirriez,V.; Welle, A.; Vantomme, A.; Kirillov, E ; Carpentier, J.-F.; Afonso, C.; Giusti, P. Anal. Chem. 2020, 92, 2922-2925. DOI link
88.	“Zirconocene-Catalyzed Polymerization of α-Olefins: When Intrinsic Higher Activity is Flawed by Rapid Deactivation”. Desert, X.; Proutiere, P.; Welle, A.; Den Dauw, K.; Vantomme, A.; Miserque, O.; Brusson, J.-M.; Carpentier, J.-F.; Kirillov, E. Organometallics 2019, 38, 2664-2673.
87.	“Quantification of Active Sites in Single-Site Group 4 Metal Olefin Polymerization Catalysis”. Desert, X.; Carpentier, J.-F.; Kirillov, E. Coord. Chem. Rev. 2019, 386, 50-68.
86.	“Synthesis, APPI Mass-Spectrometric Characterization, and Polymerization Studies of Group 4 Dinuclear Bis(ansa-metallocene) Complexes”. Schnee, G.; Farenc, M.; Bitard L.; Vantomme, A.; Welle, A.; Brusson, J.-M.; Afonso, C.; Giusti, P.; Carpentier, J.-F.; Kirillov, E. Catalysts 2018, 8, 558-577.
85.	“Trinuclear Tris(ansa-metallocene) complexes of Zirconium and Hafnium for Olefin Polymerization”. Jende, L.; Vantomme, A.; Welle, A.; Brusson, J.-M.; Carpentier, J.-F.; Kirillov, E. J. Organomet. Chem. 2018, 878, 19-29.
84.	“A Theoretical Outlook on the Stereoselectivity Origins of Isoselective Zirconocene Propylene Polymerization Catalysts”. Castro, L.; Therukauff, G.; Vantomme, A.; Welle, A.; Haspeslagh, L.; Brusson, J.-M.; Maron, L.; Carpentier, J.-F.; Kirillov, E. Chem. Eur. J. 2018, 24, 10784-10792.
83.	“Stereoselective Copolymerization of Styrene with Terpenes Catalyzed by an Ansa-Lanthanidocene Catalyst: Access to New Syndiotactic Polystyrene-Based Materials”. Laur, E.; Welle, A.; Vantomme, A.; Miserque, O.; Brusson, J.-M.; Carpentier, J.-F.; Kirillov, E. Catalysts 2017, 7, 361.
82.	“Synthesis and Structural Characterization of Zirconium Complexes Supported by Tridentate Pyrrolide-Imino Ligands with Pendant N-, O- and S-donor Groups and Their Application in Ethylene Polymerization”. Pinheiro, A.; Da Silva, S. M.; Roisnel, T.; Kirillov, E.; Carpentier, J.-F.; Casagrande, O. L. Jr. New J. Chem. 2017, 2017, 42, 1477-1483.
81.	“Experimental and Computational Investigations on Highly Syndioselective Styrene-Ethylene Copolymerization Catalyzed by Allyl ansa-Lanthanidocenes”. Louyriac, E.; Laur, E.; Welle, A.; Vantomme, A.; Miserque, O.; Brusson, J.-M.; Maron, L.; Carpentier, J.-F.; Kirillov, E. Macromolecules 2017, 50, 9577-9578.
80.	“Substitution Effects in Highly Syndioselective Styrene Polymerization Catalysts Based on Single-Component Allyl ansa-Lanthanidocenes: An Experimental and Theoretical Study”. Laur, E.; Louyriac, E.; Dorcet, V.; Welle, A.; Vantomme, A.; Miserque, O.; Brusson, J.-M.; Maron, L.; Carpentier, J.-F.; Kirillov, E. Macromolecules, 2017, 50, 6539-6551.
79.	“Engineering of Syndiotactic and Isotactic-Polystyrene Based Copolymers via Stereoselective Catalytic Polymerization”. Laur, E.; Kirillov, E.; Carpentier, J.-F. Molecules 2017, 22, 594-625.
78.	“Conformationally Dynamic Titanium and Zirconium Cationic Complexes of Bis(naphthoxy)pyridine ligands: Structure, “Oscillation” and Olefin Polymerization Catalysis”. Annunziata, L.; Roisnel, T.; Razavi, A.; Carpentier, J.-F.; Kirillov, E. Dalton Trans. 2017, 46, 3150-3159.
77.	“Polymerization of Sterically Hindered Alpha-Olefins with Single-Site Group 4 Metal Catalyst Precursors”. Theurkauff, G.; Den Dauw, K.; Miserque, O.; Vantomme, A.; Brusson, J.-M.; Carpentier, J.-F.; Kirillov, E. Polyolefins Journal 2017, 4, 123-126.
76.	“Scandium and Yttrium Complexes of an Hybrid Phenoxy-Amidopyridinate Ligand. Use in ROP of Racemic Lactide”. El Haj Hassan, J.; Radkov, V.; Dorcet, V.; Carpentier, J.-F.; Kirillov, E. J. Organomet. Chem. 2016, 823, 34-39.
75.	“Synthesis and Structure of First Discrete Dinuclear Cationic Aluminum Complexes”. Wang, X.; Dorcet, V.; Luo, Y.; Carpentier, J.-F.; Kirillov, E. Dalton Trans. 2016, 45, 12345-12351.
74.	“Yb(II) Triple-Decker Complex with the μ-Bridging Naphthalene Dianion [CpBn5Yb(DME)]2(μ-η4:η4-C10H8). Oxidative Substitution of [C10H8]2– by 1,4-Diphenylbuta-1,3-diene and P4 and Protonolysis of the Yb–C10H8 Bond by PhPH2”. Selikhov, A. N.; Mahrova, T. V.; Cherkasov, A. V.; Fukin, G. K.; Kirillov, E.; Lamsfus, C. A.; Maron, L.; Trifonov, A. A. Organometallics 2016, 35, 2401-2409.
73.	“Tandem C(sp2)–OMe Activation / C(sp2)–C(sp2) Coupling in Early Transition Metal Complexes: Aromatic C−O Activation beyond Late Transition Metals”. Radkov, V.; Roisnel, T.; Trifonov, A.; Carpentier, J.-F.; Kirillov, E. J. Am. Chem. Soc. 2016,138, 4350-4353.
72.	"Highly Stereocontrolled Ring-Opening Polymerization of racemic-Alkyl beta-Malolactonates Mediated by Yttrium [Amino-alkoxy-bis(phenolate)] Complexes". Jaffredo, C. G. ; Chapurina, Y. ; Kirillov, E.; Carpentier, J.-F.; Guillaume, S. M. Chem. Eur. J., 2016, 22, 7629-7641.
71.	“Discrete Ionic Complexes of Highly Isoselective Zirconocenes. Solution Dynamics, Trimethylaluminum Adducts, and Implications in Propylene Polymerization”. Theurkauff, G.; Bader, M.; Marquet, N.; Bondon, A.; Roisnel, T.; Guegan, J.-P.; Amar, A.; Boucekkine, A.; Carpentier, J.-F.; Kirillov, E. Organometallics, 2016, 35, 258-276.
70.	“Ni(II) complexes bearing pyrrolide-imine ligands with pendant N-, O- and S-donor groups: synthesis, structural characterization and use in ethylene oligomerization”. Pinheiro, A. C.; Virgili, A. H.; Roisnel, T.; Kirillov, E.; Carpentier, J.-F.; Casagrande, O. L., Jr. RSC Advances 2015, 5, 91524-91531.
69.	“Carboxylic acid derivatives via catalytic carboxylation of unsaturated hydrocarbons: whether the nature of a reductant may determine the mechanism of CO2 incorporation?” Kirillov, E.; Carpentier, J.-F.; Bunel E. Dalton Trans. 2015, 44, 16212-16223.
68.	“Ethylene oligomerization promoted by chromium complexes bearing pyrrolide–imine–amine/ether tridentate ligands”. Pinheiro, A. C.; Roisnel, T.; Kirillov, E.; Carpentier, J.-F.; Casagrande, O. L. Dalton Trans. 2015, 44, 16073-16080.
67.	”Heterobi- and -trimetallic Ion Pairs of Zirconocene-Based Isoselective Olefin Polymerization Catalysts with AlMe3”. Theurkauff, G.; Bondon, A.; Dorcet, V.; Carpentier, J.-F.; Kirillov, E. Angew. Chem. Int. Ed. 2015, 54, 6343-6346.
66.	”Beyond Stereoselectivity, Switchable Catalysis: Some of the Last Frontier Challenges in Ring-Opening Polymerization of Cyclic Esters”. Guillaume, S. M.; Kirillov, E.; Sarazin, Y.; Carpentier, J.-F. Chem. Eur. J. 2015, 21, 7988-8003.
65.	”Syndioselective ring-opening polymerization and copolymerization of trans-1,4-cyclohexadiene carbonate mediated by achiral metal- and organo-catalysts”. Diallo, A. K.; Kirillov, E.; Slawinski, M.; Brusson, J.-M.; Guillaume, S. M.; Carpentier, J.-F. Polymer Chem. 2015, 6, 1961-1971.
64.	”Are Solvent and Dispersion Effects Crucial in Olefin Polymerization DFT Calculations? Some Insights from Propylene Coordination and Insertion Reactions with Group 3 and 4 Metallocenes”. Castro, L.; Kirillov, E.; Miserque, O.; Welle, A.; Haspeslagh, L.; Carpentier, J.-F.; Maron, L. ACS Catalysis 2015, 5, 416-425.
63.	“Zinc, aluminum and group 3 metal complexes of sterically demanding naphthoxy-pyridine ligands: Synthesis, structure, and use in ROP of racemic lactide and β-butyrolactone”. Chapurina, Y.; Roisnel, T.; Carpentier, J.-F.; Kirillov, E. Inorg. Chim. Acta 2014, 431, 161-175.
62.	“iPP-sPP Stereoblocks or Blends? Studies on the Synthesis of Isotactic-Syndiotactic Polypropylene Using Single C1- Symmetric {Ph2C-(Flu)(3-Me3Si-Cp)}ZrR2 Metallocene Precatalysts”. Theurkauff, G.; Roisnel, T.; Waassenaar, J.; Carpentier, J.-F.; Kirillov, E. Macromol. Chem. Phys. 2014, 215, 2035-2047.
61.	“Zirconocene-catalyzed stereoselective cyclocopolymerization of 2-methyl-1,5-hexadiene with propylene”. Bader, M.. Theurkauff, G.; Den Dauw, K.; Lamotte, C.; Lhost, O.; Kirillov, E.; Carpentier, J.-F. Polymer Chem. 2014, 5, 5560-5568.
60.	“Scandium versus yttrium{amino-alkoxy-bis(phenolate)} complexes for the stereoselective ring-opening polymerization of racemic lactide and β-butyrolactone”. Chapurina, Y.; Klitzke, J.; de L. Casagrande, O., Jr.; Awada, M.; Dorcet, V.; Kirillov, E.; Carpentier, J.-F. Dalton Trans. 2014, 43, 14322-14333.
59.	"Enantiopure Isotactic PCHC synthesized by Ring-Opening Polymerization of Cyclohexene Carbonate". Guerin, W.; Diallo, A. K.; Kirillov, E.; Helou, M.; Slawinsky, M.; Brusson, J.-M.; Carpentier, J.-F.; Guillaume, S. M. Macromolecules 2014, 47, 4230-4235.
58.	“Neutral and Cationic Alkyl and Amido Group 3 Metal Complexes of Amidine-Amidopyridinate Ligands: Synthesis, Structure and Polymerization Catalytic Activity”. Rad’kov, V.; Roisnel, T.; Trifonov, A.; Carpentier, J.-F.; Kirillov, E. Eur. J. Inorg. Chem. 2014, 25, 4168-4178.
57.	“Discrete O-Lactate and β-Alkoxybutyrate Aluminum Pyridine–Bis(naphtholate) Complexes: Models for Mechanistic Investigations in the Ring-Opening Polymerization of Lactides and β-Lactones”. Klitzke, J. S.; Roisnel, T.; Kirillov, E.; Casagrande Jr, O. de L.; Carpentier, J.-F. Organometallics 2014, 33, 5693-5707.
56.	“Yttrium- and Aluminum-Bis(phenolate)pyridine Complexes: Catalysts and Model Compounds of the Intermediates for the Stereoselective Ring-Opening Polymerization of racemic Lactide and -Butyrolactone”. Klitzke, J. S. ; Roisnel, T. ; Kirillov, E. ; Casagrande Jr, O. de L. ; Carpentier, J.-F. Organometallics 2014, 33, 309-321.
55.	“Dinuclear vs. Mononuclear Complexes: Accelerated, Metal-dependent Ring-Opening Polymerization of Lactide”. Normand, M.; Roisnel, T.; Carpentier, J.-F.; Kirillov, E. Chem. Commun. 2013, 49, 11692-11694.
54.	“{Phenoxy-Imine}-Aluminum versus Indium Complexes for the immortalROP of Lactide. Different Stereocontrol, Different Mechanisms”. Normand, M.; Dorcet, V.; Kirillov, E.; Carpentier, J.-F. Organometallics 2013, 32, 1694-1709.
53.	“Gallium and Indium Complexes for Ring-Opening Polymerization of Cyclic Ethers, Esters and Carbonates”. Dagorne, S.; Normand, M.; Kirillov, E.; Carpentier, J.-F. Coord. Chem. Rev. 2013, 257, 1969-1886.
52.	“Alkyl Yttrium Complexes of Amidine-amidopyridinate Ligands. Intramolecular C(sp3)-H Activation and Reactivity Studies”. Radkov, V.; Roisnel, T.; Trifonov, A.; Carpentier, J.-F.; Kirillov, E. Organometallics 2013, 32, 1517-1527.
51.	“Old and New C1-Symmetric Group 4 Metallocenes {(R1R2C)-(R2’R3’R6’R7’-Flu)(3-R3-5-R4-C5H2)}ZrCl2: From Highly Isotactic Polypropylenes to Vinyl End-Capped Isotactic-Enriched Oligomers”. Bader, M.; Marquet, N.; Kirillov, E. ; Roisnel, T.; Razavi, A.; Lhost, O.; Carpentier, J.-F. Organometallics 2012, 21, 8375-8387.
50.	“Meerwein–Ponndorf–Verley-Type Reduction Processes in Aluminum and Indium Isopropoxide Complexes of Imino-Phenolate Ligands”. Normand, M.; Kirillov, E.; Roisnel, T.; Carpentier, J.-F. Organometallics 2012, 31, 5511-5519.
49.	“Synthesis and Structural Diversity of Group 4 Metal Complexes with Multidentate Tethered Phenoxy-Amidine and Phenoxy-Amidinate Ligands”. Kirillov, E.; Roisnel, T.; Carpentier, J.-F. Organometallics 2012, 31, 3228-3240.
48.	"Cyclodextrin-Centered Polyesters: Controlled Ring-Opening Polymerization of Cyclic Esters from β-Cyclodextrin-Diol". Normand, M.; Kirillov, E.; Carpentier, J.-F., Guillaume, S. Macromolecules 2012, 45, 1122-1130.
47.	"Indium Complexes of Fluorinated Dialkoxy-Diimino Salen-like Ligands for Ring-Opening Polymerization of racemic Lactide: How does Indium Compare to Aluminum?" Normand, M.; Kirillov, E. ; Roisnel, T.; Carpentier, J.-F. Organometallics 2012, 31, 1448-1457.
46.	“Lanthanide borohydrides supported by an ansa-bis(amidinate) ligand with a rigid naphthalene linker: Synthesis, structure and catalytic activity in ring-opening polymerization of lactide”. Yakovenko, M. V.; Trifonov, A. A.; Kirillov, E.; Roisnel, T.; Carpentier, J.-F. Inorg. Chem. Act, 2012, 383, 137-142.
45.	"Rare Earth Complexes with Multidentate Tethered Phenoxy-Amidinate Ligands: Synthesis, Structure and Activity in Ring-Opening Polymerization of Lactide". Sinenkov, M. ; Kirillov, E.; Roisnel, T.; Fukin, G.; Trifonov, A.; Carpentier, J.-F. Organometallics 2011, 30, 5509–5523.
44.	“Chiral-at-ansa-Bridged Group 4 Metallocene Complexes {(R1R2C)-(3,6-tBu2Flu)(3-R3-5-Me-C5H2)}MCl2: Synthesis, Structure, Stereochemistry, and Use in Highly Isoselective Propylene Polymerization”. Kirillov, E.; Marquet, N.; Bader, M.; Razavi, A.; Belia, V.; Hampel, F.; Roisnel, T.; Gladysz, J. A.; Carpentier, J.-F. Organometallics 2011, 30, 263-272.
43.	“Exploring Electronic versus Steric Effects in Stereoselective Ring-Opening Polymerization of Lactide and b-Butyrolactone with Amino-Alkoxy-Bis(phenolate) Yttrium Complexes”. Bouyahyi, M. ; Ajellal, N.; Kirillov, E.; Thomas, C. M. ; Carpentier, J.-F. Chem. Eur. J. 2011, 17, 1872-1883.
42.	“New C1-Symmetric Ph2C-bridged multisubstituted ansa-zirconocenes for highly isospecific propylene polymerization: synthetic approach via activated fulvenes”. Kirillov, E.; Marquet, N.; Razavi, A.; Belia, V.; Hampel, F.; Roisnel, T.; Gladysz, J. A.; Carpentier, J.-F. Organometallics 2010, 29, 5379-5382.
41.	“A DFT investigation of the tacticity control during styrene polymerization catalyzed by single-component allyl ansa-lanthanidocenes {(C5H4-CMe2(9-C13H8)}Ln(C3H5)”. Perrin, L.; Kirillov, E.; Carpentier, J.-F.; Maron, L. Macromolecules 2010, 43, 6330-6336.
40.	“Discrete allyl complexes of group 3 metals and lanthanides”. Carpentier, J.-F., Guillaume, S.; Kirillov, E.; Sarazin, Y. Compt. Rend. Chimie 2010, 13, 608-625.
39.	“Group 3 metal complexes supported by tridentate pyridine- and thiophene-linked bis(naphtholate) ligands: synthesis, structure, and use in stereoselective ring-opening polymerization of racemic lactide and beta-butyrolactone”. Grunova, E.; Kirillov, E.; Roisnel, T.; Carpentier, J.-F. Dalton Trans. 2010, 39, 6739-6752.
38.	“Group 4 post-metallocene complexes incorporating tridentate silyl-substituted bis(naphthoxy)pyridine and bis(naphthoxy)thiophene ligands: probing systems for ”oscillating” olefin polymerization catalysis”. Kirillov, E.; Roisnel, T.; Razavi, A.; Carpentier, J.-F. Organometallics 2009, 28, 5036-5051.
37.	"Chromium(III) complexes of sterically crowded bidentante {ONR} and tgridentate {ONNR} naphthoxy-imine ligands: syntheses, structures and use in ethylene oligomerization”. Kirillov, E.; Roisnel, T.; Razavi, A.; Carpentier, J.-F. Organometallics 2009, 28, 2401-2409.
36.	“On the initiation mechanism of syndiospecific stryrene polymerization catalyzed by single-component ansa-lanthanidocenes”. Perrin, L; Sarazin, Y.; Kirillov, E.; Carpentier, J.-F.; Maron, L. Chem. Eur. J. 2009, 15, 3773-3783.
35.	“Group 4 Metal Complexes of Fluorous (Di)Alkoxide-(Di)Imino Ligands: Synthesis, Structure, Olefin Polymerization Catalysis, and Decomposition Pathways”. Marquet, N.; Kirillov, E.; Roisnel, T.; Razavi, A.; Carpentier, J.-F. Organometallics 2009, 28, 606-620.
34.	“Group 3 metal complexes of salen-like fluorous dialkoxy-diimino ligands: synthesis, structure and application in ring-opening polymerization of rac-lactide and rac-b-butyrolactone". Grunova, E.; Kirillov, E.; Roisnel, T.; Carpentier, J.-F. Organometallics 2008, 27, 5691-5698.
33.	“Aluminum complexes of fluorinated dialkoxy-diimino salen-like ligands: syntheses, structures and use in ring-opening polymerization of cyclic esters”. Bouyahyi, M.; Grunova, E.; Marquet, N.; Kirillov, E.; Thomas, C.M.; Roisnel, T.; Carpentier, J.-F. Organometallics 2008, 27, 5815-5825.
32.	“Stereocontrolled styrene-isoprene copolymerization and styrene-ethylene-isoprene terpolymerization with a single-component allyl ansa-Neodymocene Catalyst”. Rodrigues, A.-S.; Kirillov, E.; Vuillemin, B.; Razavi, A.; Carpentier, J.-F. Polymer 2008, 49, 2039-2045.
31.	“Modified Syndiotactic Polystyrenes from Single-Site Rare-Earth Catalysts”. Kirillov,E.; Carpentier, J.-F. Chem. Today 2008, 26, 60-62.
30.	“Synthesis, structures, dynamics and ethylene polymerization activity of nickel complexes containing an ortho-methoxy-aryl diphosphine ligand”. Lavanant, L.; Rodrigues, A.-S.; Kirillov, E.; Carpentier, J.-F.; Jordan, R.F. Organometallics 2008, 27, 387-393.
29.	“Haptotropic rearrangements in sandwich (fluorenyl)(cyclopentadienyl) iron and ruthenium complexes”. Kirillov, E.; Kahlal, S.; Roisnel, T.; Georgelin, T.; Saillard, J.-Y.; Carpentier, J.-F. Organometallics 2008, 27, 387-393.
28.	“Group 3 and 4 single-site catalysts for stereospecific polymerization of styrene”. Rodrigues, A.-S.; Kirillov, E.; Carpentier, J.-F. Coord. Chem. Rev. 2008, 252, 2115-2136.
27.	“Convenient synthesis of mono- and di-β-hydroxy-β-bis(trifluoromethyl)-(di)imines from β-hydroxy-β-bis(trifluoromethyl)-ketones and (di)amines”. Marquet, N.; Grunova, E.; Kirillov, E.; Bouyahyi, M.; Thomas, C. M.; Carpentier, J.-F. Tetrahedron 2008, 64, 75-83.
26.	“Highly isospecific styrene polymerization catalyzed by single-component bridged bis(indenyl) allyl group 3 complexes”. Rodrigues, A.-S.; Kirillov, E.; Roisnel, T.; Vuillemin, B.; Razavi, A.; Carpentier, J.-F. Angew. Chem. Int. Ed. 2007, 46, 7240-7245.
25.	“Binary ansa-lanthanidocenes/dialkylmagnesium systems versus single-component catalyst: controlled synthesis of end-capped syndiotactic oligostyrenes”. Rodrigues, A.-S.; Kirillov, E.; Vuillemin, B.; Razavi, A.; Carpentier, J.-F. J. Mol. Cat. Ser. A. 2007, 273, 87-91.
24.	“Allyl ansa-lanthanidocenes: single-component, single-site catalysts for controlled syndiospecific styrene and styrene-ethylene (co)polymerization”. Rodrigues, A.-S.; Kirillov, E.; Roisnel, T.; Lehmann, C. W.; Vuillemin, B.; Razavi, A.; Carpentier, J.-F. Chem. Eur. J. 2007, 13, 5548-5565.
23.	“Chiral fluorous dialkoxy-diamino zirconium complexes: synthesis and use in stereospecific polymerization of 1-hexene”. Kirillov, E.; Lavanant, L.; Thomas, C.T.; Roisnel, T.; Chi, Y.; Carpentier, J.-F. Chem. Eur. J. 2007, 13, 786-791.
22.	“Syndiotactic-enriched propylene-styrene copolymers using fluorenyl-based half-titanocene catalysts”. Kirillov, E.; Razavi, A.; Carpentier, J.-F. J. Mol. Cat. Ser. A : Chem. 2006, 249, 230-235.
21.	“Ansa-metallocene and half-sandwich somplexes of group 3 metals and lanthanides incorporating fluorenyl-based ligands: from synthesis to catalytic applications”. Kirillov, E.; Dash, A. K.; Rodrigues, A.-S.; Carpentier, J.-F. Compt. Rend. Chimie 2006, 9, 1151-1157.
20.	“Groups 2 and 3 metal complexes incorporating fluorenyl ligands”. Kirillov, E.; Saillard, J.-Y.; Carpentier, J.-F. Coord. Chem. Rev. 2005, 249, 1221-1248.
19.	“Highly syndiospecific polymerization of styrene catalyzed by allyl lanthanide complexes”. Kirillov, E.; Lehmann, C. W.; Razavi, A.; Carpentier, J.-F. J. Am. Chem. Soc. 2004, 126, 12240-12241.
18.	“Synthesis, structure and polymerization activity of neutral halide, alkyl and hydrido yttrium complexes of isopropylidene-bridged cyclopentadienyl-fluorenyl ligands”. Kirillov, E.; Lehmann, C. W.; Razavi, A.; Carpentier, J.-F. Organometallics 2004, 23, 2768-2777.
17.	“[η5:η1-(3,6-tBu2Flu)SiMe2NtBu]Y(η1-NC5H6)(py)2: a 1,4-hydride addition product to pyridine that brings evidence for the first group 3 metal fluorenyl-hydrido complex”. Kirillov, E.; Lehmann, C. W.; Razavi, A.; Carpentier, J.-F. Eur. J. Inorg. Chem. 2004, 943-945.
16.	“[(Cp-CMe2-Flu)2Ln]–[Li(ether)n]+ (Ln = Y, La): complexes with unusual coordination modes of the fluorenyl ligand and the first examples of lis(ansa)lanthanidocenes”. Kirillov, E.; Toupet, V.; Lehmann, C. W.; Razavi, A.; Kahlal, S.; Saillard, J.-Y.; Carpentier, J.-F. Organometallics 2003, 22, 4038-4046.
15.	“Group 3 metal "constrained geometry" complexes of the fluorenyl-based ligands [(3,6-tBu2Flu)SiR2NtBu]: synthesis, structural characterization and polymerization activity”. Kirillov, E.; Toupet, L.; Lehmann, C. W.; Razavi, A.; Carpentier, J.-F. Organometallics 2003, 22, 4467-4479.
14.	“A new half-sandwich Yb(II) complex with the tridentate cyclopentadienyl ligand [C5H4CH2CH(O)CH2OBu]2-: synthesis, self-assembly of a tetranuclear cuban-like framework {[(η5-C5H4)CH2CH(η1-O)CH2O-nBu)]Yb}4 and oxidative alkylation by Me2Hg to the Yb(III) derivative [(η5-C5H4)CH2CH(η1-O)CH2O-nBu]YbMe(thf)”. Trifonov, A.A.; Kirillov, E.; Fischer, A.; Edelmann, F. T.; Bochkarev, M.N. J. Organomet. Chem. 2002, 647, 94-99.
13.	“Half-sandwich complexes of lanthanides with tridentate ligands [RCH2CH(O)CH2OBu]2- (R = C5H4, 1-C9H6): synthesis, structures, and properties. The crystal structure of the complex {[(η5-C5H4)CH2CH(η2:η1-O)CH2OBu]LaN(SiMe3)2}2”. Trifonov, A. A.; Fedorova, E. A.; Kirillov, E.; Nefedov, S. E.; Eremenko, I. L.; Kurskii, Yu. A.; Shavyrin, A. S.; Bochkarev, M. N. Russ. Chem. Bull. 2002, 51, 684-690.
12.	“Catalytic activity of some organolanthanoid derivatives in the styrene and propene polymerization”. Kirillov, E.; Fedorova, E.A.; Trifonov, A.A.; Bochkarev, M.N. Appl. Organomet. Chem. 2001, 15, 151-156.
11.	“Fluorenyl and ansa-dimethylsilyl-bis(fluorenyl) derivatives of divalent ytterbium and samarium - synthesis and structure of the first mixed – ligand LnII classic sandwich complex (C13H9)(C5Me5)Yb(DME)”. Trifonov, A.A.; Kirillov, E.; Dechert, S.; Schumann, H.; Bochkarev, M.N. Eur. J. Inorg. Chem. 2001, 2509-2514.
10.	“(C9H7)YbI(DME)2, the first indenyl half-sandwich complex of divalent ytterbium”. Trifonov, A.A.; Kirillov, E.; Dechert, S.; Schumann, H.; Bochkarev, M.N. Eur. J. Inorg. Chem. 2001, 12, 3055-3058.
9.	“Interaction of the naphthalene ytterbium complex C10H8Yb(THF)2 with cyclopentadienyl-substituted alkohols and amines – a convenient synthetic route to half-sandwich complexes of divalent ytterbium”. Trifonov, A.A.; Kirillov, E.; Kurskii, Yu.A.; Bochkarev, M. N. Rus. Chem. Bull. 2000, 49, 4-5.
8.	“Molecular hydrides of samarium and europium LnH2(THF)2 (Ln = Sm, Eu): synthesis and properties”. Fedorova, E.A.; Trifonov, A.A.; Kirillov, E.; Bochkarev, M.N. Rus. Chem. Bull. 2000, 49, 946-948.
7.	“Investigation of reactions of some halides, cyclopentadienyl-dichlorides and biscyclopentadienylchlorides of lanthanides with radical-anion adducts of trans-stilbene and alkaline metals [PhCHCHPh]-.M+ (M = Li, Na)”. Trifonov, A.A.; Fedorova, E.A.; Kirillov, E.; Girgsdies, F.; Schumann, H.; Bochkarev, M.N. Rus. Chem. Bull. 2000, 49, 1436-1439.
6.	“Attempted synthesis of divalent neodymium derivatives. crystal structure of the Nd(III) complex [{NdCl2(2,4,6-tBu3C6H2O)(μ-Cl)(THF)}Li(THF)2]2”. Kirillov, E.; Trifonov, A.A.; Nefedov, S.E.; Eremenko, I.L.; Edelmann, F.T.; Bochkarev, M.N. Z. Naturforsch. 1999, 54b, 1379-1384.
5.	“Divalent compounds of thulium, neodymium, and dysprosium”. Bochkarev, M.N.; Fagin, A.A.; Fedushkin, I.L.; Trifonov, A.A.; Kirillov, E.; Eremenko, I.L.; Nefedov, S.E. Materials Science Forum 1999, 315-317, 144-153.
4.	“A new bifunctional ligand: C5Me4HSiMe2OSiMe2O2-. Synthesis, properties and crystal structure of the first Yb(II) half-sandwich complex with a heterobidentate cyclopentadienyl ligand, [{(η5-C5Me4)SiMe2OSiMe2(η1-O)}Yb(thf)]2”. Trifonov, A.A.; Kirillov, E.; Fischer, A.; Edelmann, F.T.; Bochkarev, M.N. Chem. Commun. 1999, 2203-2204.
3.	“Synthesis, properties and crystal structure of complex Cp2Yb(DAD)”. Trifonov, A. A.; Kirillov, E.; Bochkarev, M. N.; Schumann, H.; Muehle, S. Rus. Chem. Bull. 1998, 48, 382.
2.	“Synthesis, properties and reactivity of stilbene ytterbium complex (PhCHCHPh)Yb(THF)3. Crystal structure of (2,4,6-But3C6H2O)2Yb(THF)3“. Trifonov, A. A.; Kirillov, E.; Fedorova, E.A.; Makarenko, N.P.; Bochkarev, M. N.; Schumann, H.; Muehle, S. Rus. Chem. Bull. 1998, 47, 2274-2279.
1.	“Oxidation of magnesium in the presence of coordinating solvents“. Maslennikov, S.V.; Kirillov, E.; Berezina, N.V.; Spirina, I.V.; Kondin, A.V. Rus. J. General Chem. 1997, 67, 667-671.

PATENTS

27.

“Dual Catalyst Compositions and Polymerization Process”.
Giffin, K.; Carpentier, J.-F.; Kirillov, E.; Welle, A.; Cirriez, V. (Univ. Rennes 1, CNRS et TotalEnergies OneTech Belgium)
PCT Int. Appl. WO2023099528 (08/06/2023).

26.

"Dual Catalyst Compositions”.
Giffin, K.; Carpentier, J.-F.; Kirillov, E.; Welle, A.; Cirriez, V. (Univ. Rennes 1, CNRS et TotalEnergies OneTech Belgium)
PCT Int. Appl. WO2023099525 (08/06/2023).

25.

“New Metallocene Catalyst and Use Thereof (Cp-Indenyl)”.
Coustham, T.; Carpentier, J.-F.; Kirillov, E.; Theodosopoulou, D.; Welle, A.; Piola, L.
Eur. Pat. Appl. 21 305704.5 (27/05/2021).

24.

“Process for Preparing Propylene Polymers Having Long Chain Branches (1,7-octadiene)“.
Welle, A.; Carpentier, J.-F. ; Kirillov, E.; Piola, L.; Santoro, O.
Eur. Pat. Appl. 20 305907.6 (06/08/2020).

23.

“Process for Preparing Ethylene Polymers Having Long Chain Branches (octenyl-Al).“
Welle, A.; Carpentier, J.-F. ; Kirillov, E.; Piola, L.; Santoro, O.
Eur. Pat. Appl. 20 305906.8 (06/08/2020).

22.

“New compounds suitable as catalysts for polymerization reactions”.
Welle, A.; Vantomme, A.; Carpentier, J.-F.; Nuria, R.; Kirillov, E.
PCT Int. Appl. 2019, WO 2019048561 A1 20190314.

21.

“Process for preparing polypropylene using bis(metallocene) catalysts”.
Welle, A.; Vantomme, A.; Carpentier, J.-F.; Schnee, G.; Miserque, O.; Kirillov, E.
PCT Int. Appl. 2018, WO 2018046568 A1 20180315.

20.

“Process for preparing polyethylene using bis(metallocene) compound catalysts”.
Welle, A.; Vantomme, A.; Carpentier, J.-F.; Schnee, G.; Miserque, O.; Kirillov, E
PCT Int. Appl. 2018, WO 2018046567 A1 20180315.

19.

“Process for preparing polyethylene using bis(metallocene) compound catalysts”.
Welle, A.; Vantomme, A.; Carpentier, J.-F.; Schnee, G.; Miserque, O.; Kirillov, E.
PCT Int. Appl. 2018, WO 2018046566 A1 20180315.

18.

“Long-chain-branched polypropylene prepared with metallocene-based active catalyst systems”.
Bader, M.; Carpentier, J.-F.; Kirillov, E.; Lhost, O.; Lamotte, C.; Den Dauw, K.
PCT Int. Appl. 2015, WO 2015082709 A1 20150611.

17.

“Polypropylene having improved elongational properties”.
M. Bader, J.-F. Carpentier, E. Kirillov, O. Lhost, D. Ribour, (Univ. Rennes 1 et Total Petrochemicals)
Eur. Pat. Appl. (28/10/2011) EP11290503.9-2109; PCT Int. Appl. 2013, WO 2013060810 A1.

16.

“Preparation of Long-Chain Branched Isotactic Polypropylene”.
J.-F. Carpentier, E. Kirillov, N. Marquet, A. Razavi (Univ. Rennes 1 et Total Petrochemicals)
Eur. Pat. Appl. (16/06/2010) EP2196481A1.

15.

“Preparation of mono-aryl-substituted methylene-bridged substituted cyclopentadienyl-fluorenyl ligands and zirconium complexes derived thereof”.
J.-F. Carpentier, E. Kirillov, N. Marquet, A. Razavi (Univ. Rennes 1 et Total Petrochemicals)
Eur. Pat. Appl. (12/12/2008), EP-08291192.6.

14.

“Sterically encumbered bidentate and tridentate naphthoxy-imine metallic complexes“.
J.-F. Carpentier, E. Kirillov, A. Razavi (Univ. Rennes 1 et Total Petrochemicals)
Eur. Pat. Appl. (28/04/2008), 08/290410.3.

13.

“Post-Metallocene complexes based on bis(naphthoxy)pyridine and bis(naphthoxy)thiophene ligands for the polymerisation of ethylene and alpha-olefins”.
J.-F. Carpentier, E. Kirillov, A. Razavi (Univ. Rennes 1 et Total Petrochemicals)
Eur. Pat. Appl. (25/02/2008), 08/290185-1.

12.

“Group 3 post-metallocene complexes based on bis(naphthoxy)pyridine and bis(naphthoxy)thiophene ligands for the ring-opening polymerisation of polar cyclic monomers“.
J.-F. Carpentier, E. Kirillov, A. Razavi (Univ. Rennes 1 et Total Petrochemicals)
Eur. Pat. Appl. (25/02/2008), 08/290186-9.

11.

“Neutral ansa-bis(indenyl) allyl lanthanide complexes for stereospecific polymerization of styrene“.
Carpentier, J.-F.; Rodrigues, A.-S.; Kirillov, E.; Razavi, A. (Univ. de Rennes 1 and Total Petrochemicals)
Eur. Pat. Appl. (2007), EP1818337A1.

10.

“Preparation of styrene-isoprene and of styrene-isoprene-ethylene copolymers“.
Carpentier, J.-F.; Kirillov, E.; Rodrigues, A.-S.; Razavi, A. (Univ. de Rennes 1 and Total Petrochemicals)
Eur. Pat. Appl. (2006), EP1777240A1.

“Fluorinated alkoxy-imino olefin polymerization catalyst component“.
Carpentier, J.-F.; Kirillov, E.; Thomas, C.T.; Razavi, A. (Univ. de Rennes 1 and Total Petrochemicals)
Eur. Pat. Appl. (2006), EP06120743.7(15/09/2006). PCT Int. Appl. (20/03/2008), WO2008/031890A1.

“Fluorinated dialkoxy-diimino olefin polymerization catalyst component“.
Carpentier, J.-F.; Kirillov, E.; Thomas, C.T.; Razavi, A. (Univ. de Rennes 1 and Total Petrochemicals)
Eur. Pat. Appl. (2006), EP06120744.5 (15/09/2006), PCT Int. Appl. (20/03/2008), WO2008/031894A1.

“Preparation of diphenyl-bridged substituted cyclopentadienyl-fluorenyl ligands for polymerization catalysts”.
Kirillov, E.; Carpentier, J.-F.; Razavi, A. (Univ. de Rennes 1 and Total Petrochemicals)
Eur. Pat. Appl. (2008), EP1903061A1 (25.09.2006).

“Preparation of styrene homopolymers and styrene-ethylene copolymers using lanthanide metallocene catalyst”.
Carpentier, J.-F.; Kirillov, E.; Razavi, A. (Univ. de Rennes 1 and Atofina
Fr. Pat. Appl. n° 04/2908475 (31/03/ 2004); Eur. Pat. Appl. (2005), EP1582536A1 (10/05/2005).

“Carbon bridged cyclopentadienyl-fluorenyl ligands”.
Kirillov, E.; Gladysz, J.A.; Razavi, A. (Friedrich-Alexander Universität Erlangen-Nürnberg and Atofina)
Eur. Pat. Appl. (2005), EP05105162.1 (13/06/2005).

”Styrene-propylene copolymers”.
Carpentier, J.-F.; Kirillov, E.; Razavi, A. (Univ. Rennes 1 et Atofina)
PCT Int. Appl. (28/06/2004), WO 2005/005498.

“Group III bridged metallocenes based on cyclopentadienyl-fluorenyl ligands”.
Carpentier, J.-F.; Kirillov, E.; Razavi, A. (Univ. de Rennes 1 and Atofina)
Fr. Pat. Appl. n° 03/00086(07/01/2003); US Pat. US 7,241,849 B2 (06/01/2006).

“Group III bridged metallocenes based on cyclopentadienyl-fluorenyl ligands”.
Carpentier, J.-F.; Kirillov, E.; Razavi, A. (Univ. de Rennes 1 and Atofina)
Fr. Pat. Appl. n° 03/00918(29/01/2003); US Pat. US 7,309,748 B2 (16/11/2006).

“Group III metal complexes bearing fluorenyl-based constrained geometry ligands”.
Carpentier, J.-F.; Kirillov, E.; Razavi, A. (Univ. de Rennes 1 and Atofina)
Fr. Pat. Appl. n° 03/ 02832 (07/03/2003).

BOOK CHAPTERS


1.	Stereoselective Polymerization (chapter 3.21; pp 931-971) J.-F. Carpentier and E. Kirillov, in Science of Synthesis, Stereoselective Synthesis (3 vol), Vol. 2010/9, Ed.: J. G. de Vries, P. A. Evans, G. A. Molander; Houben-Weyl E21, Thieme, June 2011, ISBN (Americas): 9783131541314; ISBN (EUR, Asia, Africa, AUS): 9783131541314.
2.	Metal Phenolates as Polymerization Catalysts J.-F. Carpentier, E. Kirillov, Y. Sarazin, in PATAI’S Chemistry of Functional Groups, Online 2009–2012 John Wiley & Sons, Ltd. (Ed. Zabicky, J.). From Chemistry of Metal Phenolates (2014), 2, 839-911.
3.	Metallocene Catalysts for Stereospecific Olefin Polymerization E. Kirillov, in Encyclopedia of Polymers, Polymeric Materials, and Polymer Technology, Taylor & Francis Group (CRC Press - Routledge) (Ed. M. K. Mishra). In press.